Analysis of bis(trifluoromethylsulfonyl)imide-doped paramagnetic graphite intercalation compound using 19F very fast magic angle spinning nuclear magnetic resonance

Phosphorus-doped thin silica films characterized by magic-angle spinning nuclear magnetic resonance spectroscopy

High-resolution nuclear magnetic resonance spectroscopy of biological tissues using projected magic angle spinning.

High-resolution NMR spectra of materials subject to anisotropic broadening are usually obtained by rotating the sample about the magic angle, which is 54.7 degrees to the static magnetic field. In projected magic angle spinning (p-MAS), the sample is spun about two angles, neither of which is the magic angle. This provides a method of obtaining isotropic spectra while spinning at shallow angles...

Dynamic Nuclear Polarization Efficiency Increased by Very Fast Magic Angle Spinning

Dynamic nuclear polarization (DNP) has recently emerged as a tool to enhance the sensitivity of solid-state NMR experiments. However, so far high enhancements (>100) are limited to relatively low magnetic fields, and DNP at fields higher than 9.4 T significantly drops in efficiency. Here we report solid-state Overhauser effect DNP enhancements of over 100 at 18.8 T. This is achieved through the...

Suppression of sidebands in magic-angle-spinning nuclear magnetic resonance: General principles and analytical solutions

Several theoretical and experimental aspects of sideband suppression in the nuclear magnetic resonance (NMR) spectra of rotating solids are considered. The principles of sideband suppression are explored using general symmetry arguments and previous treatments are examined critically. Analytical solutions are given for sideband suppression pulse sequences employing four, five, six, and nine P p...

High-resolution magic angle spinning (1)H nuclear magnetic resonance spectroscopy metabolomics of hyperfunctioning parathyroid glands.

BACKGROUND Primary hyperparathyroidism (PHPT) may be related to a single gland disease or multiglandular disease, which requires specific treatments. At present, an operation is the only curative treatment for PHPT. Currently, there are no biomarkers available to identify these 2 entities (single vs. multiple gland disease). The aims of the present study were to compare (1) the tissue metabolom...